Following their 1-1 draw at regulation time, the game was decided on penalties.
Sambou Cissoko opened the scoring for the Malians, before James Valentine Ozornwafor drew Nigeria level.
The two teams failed to find a winner at the end of 90 minutes.
In the shootout, Nigeria converted all their five kicks while Mali scored four from the spot.
Nigeria with face Senegal in the final of the competition on Sunday.
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